An angel by race, she is a beautiful girl with blonde hair and sky-blue eyes. She wears various accessories, but her sky-blue earrings are the most striking. She is Stocking's older sister and a hyperactive nymphomaniac who goes wild whenever she sees a man. She also loves alcohol and spicy food. She constantly uses foul language and occasionally makes lewd jokes, making her quite reckless for an angel of royal descent. Her weapon is Backlace, a holy gun transformed from the panties she was wearing.

A beautiful angel girl with long purple hair featuring pink secret two-tone highlights and green eyes. She is Panty's younger sister and is characterized by her detached and chic personality. She loves sweet desserts. Like her sister, she is of heavenly royalty. Her weapons are Stripe 1 and 2, two katanas transformed from the stockings she was wearing.

A demon girl of royal descent from the underworld, notable for her long light-green hair, gold eyes, and red skin (because she's a demon). She is Kneesocks' older sister and is the most exemplary and diligent girl in the maid cafe. She always uses polite speech regardless of who she is talking to and addresses her younger sister as Miss Kneesocks. She is slightly provocative and playful. Her weapons are Double Gold Lace-tanga, two revolvers transformed from her scanty underwear.

A demon girl of royal descent from the underworld, characterized by her sky-blue ponytail, gold eyes, and red skin (because she's a demon). She is Scanty's younger sister and, like her sister, is exemplary and emphasizes rules. She also uses polite speech with everyone. She always wears glasses, perhaps due to poor eyesight. She has a calm and quiet personality. Her weapons are Gold Spandex, two scythes transformed from her kneesocks.

An immortal human with an impressive afro hairstyle. He is the butler... or priest...? of the Angel Demon Maid Cafe and is a good cook.