Family Silk (Wife) Anarchy Panty (Eldest Daughter) Anarchy Stocking (Second Daughter) Lamy (Younger Brother) Polyester (Nephew) Polyurethane (Nephew) The father of the Angel Sisters. His name comes from the fabric material, linen. His lower body is depicted like a plaster statue, and he does not wear pants. Since his wife Silk is blonde like Panty, it is highly likely he has navy hair like Stocking, but since he is bald, his exact hair color is unknown. True to being Panty's parent, he is part of a dysfunctional couple where he cheats despite having a wife, and his wife cheats in return. Their affairs were caught by paparazzi and reported in the Heaven media. When his approval rating dropped and the possibility of a coup increased, he summoned Panty and Stocking to Heaven to pass on the throne. He was deposed by the coup led by Lamy, but after the Angel Sisters thwarted the coup, he was reinstated with high support. Although he often appears scatterbrained, he showed a magnanimous side by forgiving Lamy—who almost caused a catastrophe by invading Hell—and even sending him on vacation to spend time with family.

Family Linen (Husband) Anarchy Panty (Eldest Daughter) Anarchy Stocking (Second Daughter) Lamy (Brother-in-law) Polyester (Nephew) Polyurethane (Nephew) The mother of the Angel Sisters and the Queen of Heaven. Her lower body is depicted in live-action. She has blonde hair and wears a mask reminiscent of Mother of Ultra, giving an overall impression similar to Angewomon. She was deposed along with her husband during Lamy's coup but was reinstated as the Queen of Heaven after the incident was resolved.

Angel Name: Pantiel Age: 1,000+ years old Species: Angel Family Anarchy Stocking (Younger Sister) Linen (Father) Silk (Mother) Lamy (Uncle) Polyester (Cousin) Polyurethane (Cousin) An angel with blonde hair and blue eyes who usually wears a red dress with a gold necklace and bracelets. She descended to the human world under orders to defeat Ghosts and collect Heaven Coins to avoid failing. She and her sister Stocking are close, even though they are always at each other's throats.

Angel Name: Stockiel Age: 1,000+ years old Species: Angel Family Anarchy Panty (Older Sister) Linen (Father) Silk (Mother) Lamy (Uncle) Polyester (Cousin) Polyurethane (Cousin) Anarchy Panty's younger sister. An angel with a navy-pink secret two-tone hairstyle, green eyes, and a Gothic Lolita style. She descended to the human world under orders to defeat Ghosts and collect Heaven Coins to avoid failing. Unlike her sister, who has an obviously open style, she enjoys Gothic Lolita fashion. Perhaps because of this, the setting is that she is much less popular than Panty. She always carries a cat plushie named Honekoneko. According to Season 2, it is a handmade doll Garterbelt made for Stocking when she was young and wouldn't come out of her room due to homesickness. She and her sister Panty are close, even though they are always at each other's throats.

Family Polyester (Eldest Son) Polyurethane (Second Son) Linen (Older Brother) Silk (Sister-in-law) Anarchy Panty (Niece) Anarchy Stocking (Niece) A high-ranking angel who is the Director of the Heaven Ethics Oversight Bureau, and the father of Polyester and Polyurethane. He is the younger brother of Linen, the King of Heaven, making him the uncle of the Angel Sisters. The Poly brothers usually call him Lord Lamy. However, during Episode 13, when he told them to call him father, they changed his title to Father Lamy. Unlike his overweight brother, he is a slender, handsome middle-aged man with long hair in a light purple-pink gradient (a mix of his sons' hair colors). He usually wears gloves, so they aren't visible, but his hands are live-action. He clearly cares for his children, but seeing how he only allowed the New Angel Brothers to call him father at the very last moment, he seems to have a personality obsessed with rules, unlike Linen. This applied to his children as well, as he appeared stiff and prioritized work over family. While Daten City is overrun by Ghosts because the Anarchy sisters are in charge, even Casino City—a place likely to have many Ghosts—had no angels other than the Poly brothers (who were there for fun). This highlights how most gods and angels, excluding Lamy, had been living dissolute lives and neglecting their duties.

Family Lamy (Father) Polyurethane (Younger Brother) Linen (Uncle) Silk (Aunt) Anarchy Panty (Cousin) Anarchy Stocking (Cousin) The older of the angel brothers who recently descended from Heaven to Daten City. He has a habit of starting his sentences with "It feels like..." He seems to have lacked affection from his strict and always busy father, yet he follows him devotedly. He also has a rather arrogant personality. As a high-ranking angel, he seems to hate demons intensely; he glared at the Demon Sisters as if he wanted to kill them the moment they appeared. He is also very competitive and tends to lose his cool when they lose or find themselves at a disadvantage.