Yurine Hanazono A student at Chimera University. Height: 160cm. The daughter of a shrine family; her family home is the Hanazono Inari Shrine in Shinjuku, Tokyo. Works part-time at "Hime-Musha," a maid cafe in Akihabara. She wears an eyepatch over her left eye and prefers Gothic Lolita fashion. Possesses enough combat ability to easily repel the demon Jashin-chan and frequently purchases weapons. Generally a sensible person with a polite demeanor toward everyone. However, her personality changes instantly if Jashin-chan plots a sneak attack or causes trouble for others.

Height: 150cm. A demon with the upper body of a blonde girl and the lower body of a snake (cobra). She believes that "clothes are for the weak," so she is basically naked, covering her chest only with her long hair. She doesn't care even if it's pointed out. Born into demon nobility, she is the daughter of the highest-ranking official in Hell's equivalent of the Ministry of Agriculture, Forestry, and Fisheries. Ends her sentences with "desu-no" (polite/feminine). She frequently attempts to kill her summoner, Yurine, by unleashing her "Dropkick" or her second killing move, "Royal Copenhagen," but is always met with a counterattack. Possesses regenerative abilities close to immortality; even if sliced by Yurine with a blade, she can heal by sealing the wound with instant glue. She takes a haughty attitude toward lower-class demons who are smaller and weaker than her, often provoking or bullying them. Her hobbies include gambling, horse racing, and pachinko. She often pesters Medusa for money. She hates wasting food.

Jashin-chan's childhood friend and a demon. Height: 155cm. Poor at cooking. Dressed in attire resembling ancient Egyptian royalty, she has the ability to petrify any human who meets her gaze. Because she would petrify everyone around her except Yurine (who carries a power stone to prevent petrification), she wears a paper bag over her head to hide her face while in the human world. She is timid, kind-hearted, and unable to say no when asked for a favor. As a result, her best friend Jashin-chan frequently begs her for money, sometimes taking all her part-time job earnings, leading Jashin-chan to call her an "ATM." If pushed to extreme anger, she enters a state known as "Honorific Medusa," where she becomes distantly polite and refuses to accept any apologies.

A demon of the Minotaur race and a childhood friend of Jashin-chan and Medusa. Height: 167cm. Characterized by her glamorous physique and the cow horns growing from her head. She has an athletic, frank, and easygoing personality. A hard worker who balances multiple physically demanding part-time jobs, such as milk delivery and construction work. Perhaps because she exerts herself so much daily, she has a massive appetite. She lives in the apartment next to Yurine.

An angel whose profession is hunting demons. Height: 148cm. She came to the human world as the Angel Commander leading the angels to subjugate Jashin-chan, but she lost her halo—the source of her power—and became unable to return to Heaven. After losing her halo, she was forced into a homeless life in the park, earning a pittance through day labor and working in harsh environments with sub-minimum wages. Constantly in extreme poverty, her staples are milk and bread crusts. When even those are unavailable, she lives off wild plants, calling it a "natural salad bar." She is cursed with misfortune, such as having her cardboard house destroyed by Jashin-chan or accidentally dropping her paycheck envelope into a donation box when she trips.

Pekola's former subordinate. Height: 156cm. Contrary to her soft and fluffy appearance, she has a black-hearted personality and a sharp tongue. She looks down on demons, calling them "inferior species with no value in living." She visited the human world to eliminate Pekola and take the position of Angel Commander, but failed when Jashin-chan interfered. She attempted a sneak attack on Jashin-chan in retaliation but was counterattacked, and Jashin-chan ate her halo. After losing her halo, she works a live-in part-time job at the ramen shop "Genesis" while performing as an idol under the name "Noel Amatsuka."

Pekola's former subordinate. Height: 160cm. Possesses a glamorous physique that rivals Minos. Skilled at making sweets. She visited the human world to eliminate Pekola and Poporon, who were wanted as rebels of Heaven. Initially, she planned to kill them both and become the Angel Commander, but she was caught off guard by Poporon, hit with a German Suplex, and had her halo destroyed, making her unable to return to Heaven. After losing her halo, she fell into despair over her failed mission and tried to take her own life. However, while wandering in the mountains, she developed the ambition to "defeat the Lord of Heaven, become the Lord herself, and rule the entire world as a queen after destroying both Heaven and the human world." While waiting for her halo to regenerate, she lives as the manager of the apartment building where Yurine and the others reside.

The Lord served by Pekola and the other angels, and the God who rules over them. Height: 130cm. Originally she has the appearance of a mature woman, but she took the form of a young child in the human world, thinking it would be less likely to arouse suspicion. Affected by her child form, she was once knocked unconscious by Yurine's full-power straight punch. In the human world, she poses as an orphan and stays at the child welfare facility "Iron Commando." She likes childish things and shows great interest in fast-food toy giveaways and playground equipment.