Male. Former leader of the Rising Volt Tacklers. Owned Pokémon: Captain Pikachu (Partner) (Electric) Charizard (Fire/Flying) Instructor Starmie (Always in Mega Evolved state) (Water/Psychic) He is easygoing and hot-blooded, with strong leadership and a sense of responsibility befitting a leader. He has a reckless side, often failing to mention important details until later, and can be surprisingly clumsy and airheaded. He is tall and has a toned physique. Currently active as an Exceed Researcher, studying Lakurium. Since the origin of Lakurium is space, he occasionally travels there. He sometimes boards the Rising Volt Tacklers' Brave Asagi to say hello. Lakurium is an ore that emits pink smoke; it is extremely dangerous, so Exceed researches and recovers it. He is Raihan's younger brother, one year his junior. The Exceed Research Lab is located near Hammerlocke Stadium in the Galar region, which is Raihan's gym.

Male. Member of the Rising Volt Tacklers. Owned Pokémon: Lucario (Shiny, capable of Mega Evolution) (Steel/Fighting) Skeledirge (Partner) (Fire/Ghost) Wattrel (Electric/Flying) He has a curious and passionate personality. He lacks caution but is free of prejudice.

Female. Member of the Rising Volt Tacklers. Owned Pokémon: Meowscarada (Partner) (Grass/Dark) Hatterene (Psychic/Fairy) Armarouge (Fire/Psychic) She is timid and cautious, but grows more courageous and resilient through her travels.

Female. Member of the Rising Volt Tacklers. Owned Pokémon: Quaquaval (Water/Fighting) Tinkaton (Steel/Fairy) Gholdengo (Steel/Ghost) She has an introverted and shy personality.

Male. Member of the Rising Volt Tacklers. Owned Pokémon: Sableye (Partner, capable of Mega Evolution) (Ghost/Dark) Dragonite (Capable of Mega Evolution) (Dragon/Flying) He is hot-tempered and boastful. He has an eccentric personality and attaches the word "Mega" to the front of every word.

Female. Member of the Rising Volt Tacklers. Owned Pokémon: Metagross (Partner) (Steel/Psychic) Elekid (Electric) She has a frank and refreshing personality. She is full of passion for machinery and her comrades.

Female. Member of the Rising Volt Tacklers. Owned Pokémon: Chansey (Partner) (Normal) Maushold (Normal) She is in charge of healing for the Rising Volt Tacklers. She is a woman of action with a warm heart who personally seeks out injured Pokémon to treat them.

Male. Member of the Rising Volt Tacklers. Owned Pokémon: Lycanroc (Midday Form) (Rock) Alcremie (Fairy) Contrary to his appearance, he has a warm and kind personality. He is usually seen eating.

Male. Member of the Rising Volt Tacklers. Owned Pokémon: Quagsire (Water/Ground) Sharpedo (Water/Dark) He has a calm and mysterious personality that reflects his years of experience.

Male. Not a member of the Rising Volt Tacklers, but the strongest Gym Leader in Galar. Owned Pokémon: Goodra (Dragon) Turtonator (Fire/Dragon) Flygon (Ground/Dragon) Duraludon (Steel/Dragon, Raihan's partner, capable of Gigantamaxing) He is a Dragon-type Gym Leader. While he trains rigorously every day, he also enjoys his hobby of social media. He is usually sly and playful, but once a battle begins, his emerald eyes, resembling a dragon's, flash with intensity. He is tall overall with a physique as toned as Friede's. He is about 1-2cm taller than Friede. He is the eldest brother, one year older than Friede.