Petelgeuse Romanee-Conti, representing "Sloth." An Evil Spirit possessing the Authority of Sloth, "Unseen Hand," which allows him to manipulate over a hundred invisible demonic hands. Furthermore, he can take over the bodies of specific individuals. He is the most active among the Sin Archbishops, a fanatic who uses "diligence" as a justification to trample over people's lives and professes a blind love for the Witch. However, in terms of being able to engage in mutual communication, he is apparently the most decent and sane among the Sin Archbishops; in fact, with anyone other than him, communication—let alone a conversation—is completely impossible.

Regulus Corneas, representing "Greed." Possessing the Authority of Greed, "Lion's Heart," he can stop the time of his own body, becoming absolutely unchanging and invincible. He possesses no love for others and is a self-centered madman who tries to settle everything with boundless self-love. He is believed to suffer from Narcissistic Personality Disorder.

Ley Batenkaitos, the "Gourmet," representing "Gluttony." An irregular Sin Archbishop who is one of a set of triplets, possessing the Authority of Gluttony's "Eating" and "Eclipse," allowing him to "consume" people's "memories" and "names." He is the eldest brother. If one's "memories" are eaten, they fall into a state of amnesia; if one's "name" is eaten, their existence is forgotten by everyone around them. That information is returned to the Archbishop himself, allowing him to exercise the prey's abilities. While their ideologies differ, all three consider others as nothing more than ingredients to satisfy their own bellies (lives), and are blasphemers who insult the thoughts and lives of people. Ley is called the "Gourmet," Roy the "Bad Eating," and Louis the "Satiation."

Roy Alphard, representing Gluttony, the "Bad Eating." The second son of the Gluttony triplets. He refers to himself as "Bad Eating" among the Gluttony siblings, and unlike Batenkaitos, he does not distinguish between "quality and quantity," devouring the lives of others indiscriminately.

Louis Arneb, representing Gluttony, "Satiation." The youngest daughter and sister to the two brothers, "Gourmet" and "Bad Eating." She is dismissive of their ideologies, saying they "don't understand a thing," and simultaneously remarks that "having incompetent brothers is a struggle." She reportedly places importance not on "what to eat," but on "who to eat with."

Sirius Romanee-Conti, representing "Wrath." A woman possessing the Authority of Wrath, "Soul Washing," which allows her to share emotions and senses to brainwash others. Due to her cruel nature of toyed with the consciousness of others, she is described as possessing "Theater-type Malice." She claims that "recognizing and understanding each other is true love," but in reality, she is a cold-hearted egoist who merely forces her own values onto others.

Capella Emerada Lugnica, representing "Lust." A girl possessing the Authority of Lust, "Variation" and "Change," which allows her to transform herself and others into various forms. She is an arrogant and cruel sadist who tramples on the dignity of others without hesitation to increase her own value, finding pleasure in thoroughly looking down on everyone but herself. She is believed to suffer from Histrionic Personality Disorder.