Naturally polite, using honorifics even with a Machop carrying luggage, but very timid. She's the type to get picked on by a Rattata eating berries nearby. Because she doesn't know what she wants to do, she often gets lost in internal monologues. She isn't used to building relationships; though she wants to be close to others, her fear of consequences makes her indecisive. She enrolled in Indigo Academy in Kanto to find her true self. After joining the Rising Volt Tacklers, she takes classes online when necessary.

Her key item is a pendant from her grandmother, designed like Terapagos's shell or a Tera Orb crystal. Solving the pendant's mystery is the core of the story, and the Explorers are targeting it. When Liko is in danger, the pendant creates a crystalline barrier, and Terapagos's Normal Form appears. It was later revealed the pendant itself is Terapagos, who now travels with her. According to Diana, it was a Pokemon that adventured with Lucius. In the second arc, Liko journeys to bring Terapagos to the paradise Lucius sought, Laqua. Partner: Sprigatito (Grass) Moves: Scratch, Leafage, Quick Attack, Magical Leaf

Other Pokemon: Hatenna (Psychic) Moves: Heal Pulse, Psychic, Magical Leaf, Refresh

The character on his shirt resembles Unown R. His name likely comes from the first letter of 'Roy'. He is around Liko's age but slightly shorter, reflecting the average height difference before puberty. In Arc 5 (one year later), he has grown taller, his hair is longer, and he wears a vest similar to Friede's ride jacket instead of a hat. He is now slightly taller than Liko.

He has a cheerful personality and is proactive in approaching others. He quickly befriended the reserved Liko and chats easily with classmates he's never met in person. He has an unbiased perspective, such as when he praised Fuecoco's singing, which Fuecoco was shy about, helping the Pokemon open up. However, he can be reckless, having broken walls twice. He sometimes ignores Friede's orders to chase Rayquaza or acts stubbornly, like sneaking onto the Brave Olivine just to see Fuecoco.

He possesses a mysterious Poke Ball found by his grandfather long ago. It has a clock-like design with red and blue spheres and visible hinges. It reacted to Liko's pendant, releasing a Black Rayquaza, revealing it belonged to an ancient adventurer. His grandfather found it on a beach as a child and knows little else about it. Partner: Fuecoco (Fire) Moves: Ember, Flamethrower, Stomping Tantrum, Flame Charge

Other Pokemon: Wattrel (Electric/Flying) Moves: Spark, Pound, Spark, Gust

Has two-tone hair like Liko and Roy—pink inside and purple outside, resembling Cherrim. She is the shortest of the Rising Volt Tacklers, even smaller than Liko and Roy, despite her uncle Murdock being the tallest. She doesn't look much like her mother, Blanca, likely inheriting her looks from her father.

Despite her age, she is a skilled content creator who produces and edits videos as 'Nidothing'. Like Clemont or Sophocles, she is a computer expert; the apps used by the crew are her creations. She handles information gathering, such as tracking the Black Rayquaza to Paldea. As a streamer, she is essentially the crew's main breadwinner.

Unlike the novice Liko and Roy, she has extensive Pokemon knowledge, but it is purely theoretical; she has zero actual battle experience. When she caught Quaxly, she panicked during battle, not knowing which moves to use. Her personality is that of a typical shut-in and outsider. She avoids direct conversation, preferring to communicate via her messaging app or by sending notes through Quaxly. She can be blunt and rude, expecting others to cater to her.

However, as Nidothing, she is high-energy and active—a complete 180-degree shift. She calls this 'switching herself on'. Despite her cold exterior, she shows a softer side, like smiling at Liko and Roy's antics or secretly enjoying Murdock's donuts at night. She has slowly begun to open up to her friends, worrying about Liko and acting to help her. Partner: Quaxly (Water) Moves: Pound, Mist, Air Slash, Low Kick

Other Pokemon: Tinkatink (Steel/Fairy) Moves: Bite, Rock Tomb, Gigaton Hammer

Has tanned skin and white hair. He wears a ride jacket with Charizard motifs instead of a lab coat. He is quite young for a professor, in his early 20s. He is hearty, passionate, and a responsible leader who cares deeply for Liko and Roy. However, he is reckless and often forgets to explain important things until the last minute.

According to Orla, he is shy about his past and bad with cameras. When Liko and Roy pressed him about Captain Pikachu's secret, he got flustered and dodged the question. He is officially recognized as a skilled battler and is passionate about it, though he knows when to retreat for the sake of the mission, especially with the Explorers lurking. He uses unconventional tactics and careful planning when needed. Partner: Pikachu (Captain) (Electric) Moves: Volt Tackle, Thunder Punch, Double Team, Thunderbolt

Other Pokemon: Charizard (Fire/Flying) Moves: Flamethrower, Dragon Claw, Air Slash, Gust, Fire Blast

Has brown hair with orange tips tied up. She handles ship repairs and fuel, often working in the engine room in heavy fireproof gear. She is exceptionally beautiful when she lets her hair down and wears casual clothes. Her partner Metagross helps move heavy materials and serves as a flying ride. It was a Metang when she first helped remodel Ludlow's fishing boat into the airship. Partner: Metagross (Steel/Psychic) Moves: Bullet Punch, Meteor Mash, Zen Headbutt, Earthquake, Agility

Responsible for the health of the crew's Pokemon. She uses Heal Pulse on wild Pokemon and restores energy using Soft-Boiled eggs. Her design—pink hair, pink outfit, and Chansey partner—strongly resembles Nurse Joy. It was eventually confirmed that she used to be a Nurse Joy. Partner: Chansey (Normal) Moves: Minimize, Soft-Boiled, Seismic Toss, Thunder Wave, Stealth Rock, Aromatherapy, Baby-Doll Eyes, Angelic Kiss

His partner Rockruff is friendly and has an excellent sense of smell. In Arc 5, it evolves into Lycanroc (Midday Form). Unlike most sleek Lycanroc, it is quite chubby because it frequently taste-tested Murdock's new sweets at the Patisserie Savonniere. Liko finds its plump form adorable. It later returned to a normal physique but kept its cheerful personality.

His other partner is Alcremie (Strawberry Sweet form), who helps him cook. It evolved from a Milcery that Murdock met. Its cream perfectly matched Murdock's dessert style, which initially caused a rift with his fellow pastry chef Mitchell, though they eventually reconciled through a 'sweets battle'. Partner: Alcremie (Fairy) Moves: Acid Armor, Decoration

Other Pokemon: Rockruff (Rock) Moves: Rock Tomb

The captain of the crew's Pokemon and Friede's partner. He wears a white captain's hat. Nicknamed 'Cap', he has a tougher look and a more serious personality than Ash's Pikachu. He acts as the face of the series, often appearing prominently in visuals. He serves as the acting captain of the Brave Olivine when Friede is away. He often sits with his arms crossed or stands on his tail.

Moves: Volt Tackle, Thunder Punch, Double Team, Thunderbolt

Unusually, he hates being inside a Poke Ball. He loves following Guest to eat Bluk Berries or finding delicious ice cream shops. Since Guest stopped going outside, he stays by their side in the room, occasionally visiting Friede or Murdock for food. He delivers notes from Guest to the crew and licks away Guest's tears to comfort them when they cry. Moves: {{Any}}

Male Age: 10 Personality: Overconfident and aggressive. He rushes into things without thinking, much like Roy used to. He is impatient and talks fast like Barry from DP—a hot-headed, simple-minded character. Appearance: Green hair, brown eyes, shorter than Dot. Has spikes on his head resembling Sableye's ears. Pokemon: Sableye (Dark/Ghost), Dragonite (Dragon/Flying)

He is a new member who acted arrogantly upon joining, claiming he would be the captain in front of veterans. He treated the observation deck like his own room and threw a tantrum when Roy called him out, even running away. He clearly needs mental growth. He has since vowed to become stronger to protect those he cares about. He is surprisingly weak against girls, getting flustered around Liko or female enemies, though he doesn't show this to Coral. He initially mistook Dot for a boy and was shocked to learn the truth.

Pokemon: Sableye (Dark/Ghost) Moves: Power Gem, Throat Chop, Confuse Ray, Shadow Sneak Dragonite (Dragon/Flying) Moves: Dragon Dive, Twister